Sum-Frequency Generation Spectra of Thin Organic Films on Silver Enhanced Due to Surface Plasmon Excitation

نویسندگان

  • E. V. Alieva
  • G. M. H. Knippels
  • A. F. G. van der Meer
  • V. A. Yakovlev
چکیده

We have studied vibrational spectra of thin films of copper phthalocyanine and fullerene of different thicknesses on silver obtained by a visible-infrared sum-frequency generation (SFG). The free electron laser FELIX was used as a source of broadband infrared and the pulsed Nd:YLF laser system as a source of visible radiation. Excitation of a surface plasmon on silver has allowed to enhance the efficiency of the SFG process. The SFG signal has appeared to be almost independent of the film thickness demonstrating the exclusive contribution of the interfacial layer to the SFG signal.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Reflectivity and transmission of amorphous thin films at the melting temperature

Related Articles Validation of a correction procedure for removing the optical effects from transmission spectra of thin films on substrates J. Appl. Phys. 112, 093514 (2012) Excitons imaging in hybrid organic-inorganic films J. Appl. Phys. 112, 093105 (2012) Comment on “Silver/silicon dioxide/silver sandwich films in the blue-to-red spectral regime with negative-real refractive index” [Appl. P...

متن کامل

Excitation of multiple dipole surface plasmon resonances in spherical silver nanoparticles.

We observe the appearance of multiple dipole surface plasmon resonances in spherical Ag nanoparticles when embedded in an organic semiconductor that exhibits a highly dispersive permittivity. Comparing the absorption spectra of thin-films with and without Ag nanoparticles reveals the presence of two plasmon peaks. Numerical simulations and calculations based on an electrostatic model allow us t...

متن کامل

SERS on mesostructured thin films with silver nanoparticles

Mesostructured 2d-hexagonal sol-gel films were prepared by dip-coating method. Their structures were detected by X-ray diffraction. Silver nanoparticles reduced from Ag ion (silver nitrate) to Ag were deposited into the channels of the structure produced by the neutral surfactant Brij58. Surface enhanced raman spectroscopy technique was used to characterize the films. Spectra of films without m...

متن کامل

Excitation of Multiple Dipole Surface Plasmon Resonances in Spherical Silver Nanoparticles Embedded in a Highly Dispersive Medium

We observe the appearance of multiple dipole surface plasmon resonances in spherical Ag nanoparticles when embedded in an organic semiconductor that exhibits a highly dispersive permittivity. Comparing the absorption spectra of thin-films with and without Ag nanoparticles reveals the presence of two plasmon peaks. Numerical simulations and calculations based ∗To whom correspondence should be ad...

متن کامل

Optimization of Sensitivity and Stability of Gold/Silver bi-Layer Thin Films Used in Surface Plasmon Resonance Chips

The aim of this study is experimental assay of sensitivity and stability of a bimetallic silver/gold SPR sensor chip. This chip utilizes the sensitivity of the silver and the stability of the gold. Moreover, the Silver layer (instead of usual Cr or Ti layer) was used as an adhesive intermediate layer between the Gold layer and the glass substrate. The optimization of the Gold/Silver thickness u...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1999